Examinando por Autor "Spezzano, S."

Mostrando 1 - 4 de 4

Acceso Abierto
Gas phase Elemental abundances in Molecular cloudS (GEMS) III. Unlocking the CS chemistry: the CS+O reaction
(EDP Sciences, 2021-02-02) Bulut, N.; Roncero, O.; Aguado, A.; Loison, J. C.; Navarro Almaida, D.; Wakelam, V.; Fuente, A.; Roueff, E.; Le Gal, R.; Caselli, P.; Gerin, M.; Hickson, K. M.; Spezzano, S.; Riviére Marichalar, P.; Alonso Albi, T.; Bachiller, R.; Jiménez Serra, I.; Kramer, C.; Tercero, B.; Rodríguez Baras, M.; García Burillo, S.; Goicoechea, J. R.; Treviño Morales, S. P.; Esplugues, G.; Cazaux, S.; Commercon, B.; Laas, J. C.; Kirk, J.; Lattanzi, V.; Martín Doménech, R.; Muñoz Caro, G. M.; Pineda, J. E.; Ward Thompson, D.; Tafalla, M.; Marcelino, N.; Malinen, J.; Friesen, R.; Giuliano, B. M.; Agúndez, Marcelino; Hacar, A.; Agencia Estatal de Investigación (AEI); Marcelino, N. [0000-0001-7236-4047]; Roncero, O. [0000-0002-8871-4846]; Pineda, J. [0000-0002-3972-1978]; Agundez, M. [0000-0003-3248-3564]; Tafalla, M. [0000-0002-2569-1253]
Context. Carbon monosulphide (CS) is among the most abundant gas-phase S-bearing molecules in cold dark molecular clouds. It is easily observable with several transitions in the millimeter wavelength range, and has been widely used as a tracer of the gas density in the interstellar medium in our Galaxy and external galaxies. However, chemical models fail to account for the observed CS abundances when assuming the cosmic value for the elemental abundance of sulfur. Aims. The CS+O → CO + S reaction has been proposed as a relevant CS destruction mechanism at low temperatures, and could explain the discrepancy between models and observations. Its reaction rate has been experimentally measured at temperatures of 150−400 K, but the extrapolation to lower temperatures is doubtful. Our goal is to calculate the CS+O reaction rate at temperatures <150 K which are prevailing in the interstellar medium. Methods. We performed ab initio calculations to obtain the three lowest potential energy surfaces (PES) of the CS+O system. These PESs are used to study the reaction dynamics, using several methods (classical, quantum, and semiclassical) to eventually calculate the CS + O thermal reaction rates. In order to check the accuracy of our calculations, we compare the results of our theoretical calculations for T ~ 150−400 K with those obtained in the laboratory. Results. Our detailed theoretical study on the CS+O reaction, which is in agreement with the experimental data obtained at 150–400 K, demonstrates the reliability of our approach. After a careful analysis at lower temperatures, we find that the rate constant at 10 K is negligible, below 10−15 cm3 s−1, which is consistent with the extrapolation of experimental data using the Arrhenius expression. Conclusions. We use the updated chemical network to model the sulfur chemistry in Taurus Molecular Cloud 1 (TMC 1) based on molecular abundances determined from Gas phase Elemental abundances in Molecular CloudS (GEMS) project observations. In our model, we take into account the expected decrease of the cosmic ray ionization rate, ζH2, along the cloud. The abundance of CS is still overestimated when assuming the cosmic value for the sulfur abundance.
Acceso Abierto
Seeds of Life in Space (SOLIS) VI. Chemical evolution of sulfuretted species along the outflows driven by the low-mass protostellar binary NGC 1333-IRAS4A
(EDP Sciences, 2020-05-15) Taquet, V.; Codella, C.; De Simone, M.; López Sepulcre, A.; Pineda, J. E.; Segura Cox, D.; Ceccarelli, C.; Caselli, P.; Gusdorf, A.; Persson, M. V.; Alves, F.; Caux, E.; Favre, C.; Fontani, F.; Neri, R.; Oya, Y.; Sakai, N.; Vastel, C.; Yamamoto, S.; Bachiller, R.; Balucani, N.; Bianchi, E.; Bizzocchi, L.; Chacón Tanarro, A.; Dulieu, F.; Enrique Romero, J.; Feng, S.; Holdship, J.; Lefloch, B.; Al Edhari, A. J.; Jiménez Serra, I.; Kahane, C.; Lattanzi, V.; Ospina Zamudio, J.; Podio, L.; Punanova, A.; Rimola, A.; Sims, I. R.; Spezzano, S.; Testi, L.; Theulé, P.; Ugliengo, P.; Vasyunin, A. I.; Vazart, F.; Viti, S.; Witzel, A.; Agence Nationale de la Recherche (ANR); European Research Council (ERC); Ceccarelli, C. [0000-0001-9664-6292]; Balucani, N. [0000-0001-5121-5683]; Rimola, A. [0000-0002-9637-4554]; Al Edhari, A. J. [0000-0003-4089-841X]; De Oliveira Alves, F. [0000-0002-7945-064X]; Lefloch, B. [0000-0002-9397-3826]; Persson, M. V. [0000-0002-1100-5734]; Bachiller, R. [0000-0002-5331-5386]; Pineda, J. [0000-0002-3972-1978]; Segura Cox, D. [0000-0003-3172-6763]; Unidad de Excelencia Científica María de Maeztu Centro de Astrobiología del Instituto Nacional de Técnica Aeroespacial y CSIC, MDM-2017-0737
Context. Low-mass protostars drive powerful molecular outflows that can be observed with millimetre and submillimetre telescopes. Various sulfuretted species are known to be bright in shocks and could be used to infer the physical and chemical conditions throughout the observed outflows. Aims. The evolution of sulfur chemistry is studied along the outflows driven by the NGC 1333-IRAS4A protobinary system located in the Perseus cloud to constrain the physical and chemical processes at work in shocks. Methods. We observed various transitions from OCS, CS, SO, and SO2 towards NGC 1333-IRAS4A in the 1.3, 2, and 3 mm bands using the IRAM NOrthern Extended Millimeter Array and we interpreted the observations through the use of the Paris-Durham shock model. Results. The targeted species clearly show different spatial emission along the two outflows driven by IRAS4A. OCS is brighter on small and large scales along the south outflow driven by IRAS4A1, whereas SO2 is detected rather along the outflow driven by IRAS4A2 that is extended along the north east–south west direction. SO is detected at extremely high radial velocity up to + 25 km s−1 relative to the source velocity, clearly allowing us to distinguish the two outflows on small scales. Column density ratio maps estimated from a rotational diagram analysis allowed us to confirm a clear gradient of the OCS/SO2 column density ratio between the IRAS4A1 and IRAS4A2 outflows. Analysis assuming non Local Thermodynamic Equilibrium of four SO2 transitions towards several SiO emission peaks suggests that the observed gas should be associated with densities higher than 105 cm−3 and relatively warm (T > 100 K) temperatures in most cases. Conclusions. The observed chemical differentiation between the two outflows of the IRAS4A system could be explained by a different chemical history. The outflow driven by IRAS4A1 is likely younger and more enriched in species initially formed in interstellar ices, such as OCS, and recently sputtered into the shock gas. In contrast, the longer and likely older outflow triggered by IRAS4A2 is more enriched in species that have a gas phase origin, such as SO2.
Acceso Abierto
Seeds of Life in Space (SOLIS) VII. Discovery of a cold dense methanol blob toward the L1521F VeLLO system.
(EDP Sciences, 2020-04-02) Favre, C.; Vastel, C.; Jiménez Serra, I.; Quénard, D.; Caselli, P.; Ceccarelli, C.; Chacón Tanarro, A.; Fontani, F.; Holdship, J.; Oya, Y.; Punanova, A.; Saki, N.; Spezzano, S.; Yamamoto, S.; Neri, R.; López Sepulcre, A.; Alves, F.; Bachiller, R.; Balucani, N.; Bianchi, E.; Bizzocchi, L.; Codella, C.; Caux, E.; De Simone, M.; Enrique Romero, J.; Dulieu, F.; Feng, S.; Al Edhari, A. J.; Lefloch, B.; Ospina Zamudio, J.; Pineda, J.; Podio, L.; Rimola, A.; Segura Cox, D.; Sims, I. R.; Taquet, V.; Testi, L.; Theulé, P.; Ugliengo, P.; Vasyunin, A. I.; Vazart, F.; Viti, S.; Witzel, A.; Agence Nationale de la Recherche (ANR); Spanish FEDER; Russian Science Foundation (RSF); European Research Council (ERC); Agencia Estatal de Investigación (AEI); Al Edhari, A. J. [0000-0003-4089-841X]; Rimola, A. [0000-0002-9637-4554]; Balucani, N. [0000-0001-5121-5683]; Ceccarelli, C. [0000-0001-9664-6292]; De Oliveira Alves, F. [0000-0002-7945-064X]; Pineda, J. E. [0000-0002-3972-1978]; Segura Cox, D. [0000-0003-3172-6763]; Bachiller, R. [0000-0002-5331-5386]; Fontani, F. [0000-0003-0348-3418]; Sakai, N. [0000-0002-3297-4497]; Unidad de Excelencia Científica María de Maeztu Centro de Astrobiología del Instituto Nacional de Técnica Aeroespacial y CSIC, MDM-2017-0737
Aims. The Seeds Of Life In Space IRAM/NOEMA large program aims at studying a set of crucial complex organic molecules in a sample of sources with a well-known physical structure that covers the various phases of solar-type star formation. One representative object of the transition from the prestellar core to the protostar phases has been observed toward the very low luminosity object (VeLLO) L1521F. This type of source is important to study to link prestellar cores and Class 0 sources and also to constrain the chemical evolution during the process of star formation. Methods. Two frequency windows (81.6–82.6 GHz and 96.65–97.65 GHz) were used to observe the emission from several complex organics toward the L1521F VeLLO. These setups cover transitions of ketene (H2CCO), propyne (CH3CCH), formamide (NH2CHO), methoxy (CH3O), methanol (CH3OH), dimethyl ether (CH3OCH3), and methyl formate (HCOOCH3). Results. Only two transitions of methanol (A+, E2) have been detected in the narrow window centered at 96.7 GHz (with an upper limit on E1) in a very compact emission blob (~7′′ corresponding to ~1000 au) toward the northeast of the L1521F protostar. The CS 2–1 transition is also detected within the WideX bandwidth. Consistently with what has been found in prestellar cores, the methanol emission appears ~1000 au away from the dust peak. The location of the methanol blob coincides with one of the filaments that have previously been reported in the literature. The excitation temperature of the gas inferred from methanol is (10 ± 2) K, while the H2 gas density (estimated from the detected CS 2–1 emission and previous CS 5–4 ALMA observations) is a factor >25 higher than the density in the surrounding environment (n(H2) ≥ 107 cm−3). Conclusions. Based on its compactness, low excitation temperature, and high gas density, we suggest that the methanol emission detected with NOEMA is (i) either a cold and dense shock-induced blob that formed recently (≤ a few hundred years) by infalling gas or (ii) a cold and dense fragment that may just have been formed as a result of the intense gas dynamics within the L1521F VeLLO system.
Restringido
The Complex Organic Molecular Content in the L1498 Starless Core
(IOP Science Publishing, 2021-08-13) Jiménez Serra, I.; Vasyunin, A. I.; Spezzano, S.; Caselli, P.; Cosentino, G.; Viti, S.; Agencia Estatal de Investigación (AEI); Ministry of Education and Science of the Russian Federation (Minobrnauka); Consejo Superior de Investigaciones Científicas (CSIC); Jiménez Serra, I. [0000-0003-4493-8714]; Vasyunin, A. I. [0000-0003-1684-3355]; Caselli, P. [0000-0003-1481-7911]; Cosentino, G. [0000-0001-5551-9502]; Viti, S. [0000-0001-8504-8844]; Unidad de Excelencia Científica María de Maeztu Centro de Astrobiología del Instituto Nacional de Técnica Aeroespacial y CSIC, MDM-2017-0737
Observations carried out toward starless and prestellar cores have revealed that complex organic molecules are prevalent in these objects, but it is unclear what chemical processes are involved in their formation. Recently, it has been shown that complex organics are preferentially produced at an intermediate-density shell within the L1544 prestellar core at radial distances of ∼4000 au with respect to the core center. However, the spatial distribution of complex organics has only been inferred toward this core, and it remains unknown whether these species present a similar behavior in other cores. We report high-sensitivity observations carried out toward two positions in the L1498 starless core, the dust peak and a position located at a distance of ∼11,000 au from the center of the core where the emission of CH3OH peaks. Similarly to L1544, our observations reveal that small O-bearing molecules and N-bearing species are enhanced by factors of ∼4–14 toward the outer shell of L1498. However, unlike L1544, large O-bearing organics such as CH3CHO, CH3OCH3, or CH3OCHO are not detected within our sensitivity limits. For N-bearing organics, these species are more abundant toward the outer shell of the L1498 starless core than toward the one in L1544. We propose that the differences observed between O-bearing and N-bearing species in L1498 and L1544 are due to the different physical structure of these cores, which in turn is a consequence of their evolutionary stage, with L1498 being younger than L1544.