Examinando por Autor "Mora, J."

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Acceso Abierto
Novel design of superhydrophobic and anticorrosive PTFE and PAA + β − CD composite coating deposited by electrospinning, spin coating and electrospraying techniques
(Multidisciplinary Digital Publishing Institute (MDPI), 2022-10-16) Vicente, Adrián; Rivero, Pedro J.; Urdiroz, U.; Mora, J.; Palacio, J. F.; Palomares, F. J.; Rodríguez, Rafael; Díaz García, Pedro; Asociación de la Industria Navarra (AIN); Agencia Estatal de Investigación (AEI)
A superhydrophobic composite coating consisting of polytetrafluoroethylene (PTFE) and poly(acrylic acid)+ β-cyclodextrin (PAA + β-CD) was prepared on an aluminum alloy AA 6061T6 substrate by a three-step process of electrospinnig, spin coating, and electrospraying. The electrospinning technique is used for the fabrication of a polymeric binder layer synthesized from PAA + β-CD. The superhydrophilic characteristic of the electrospun PAA + β-CD layer makes it suitable for the absorption of an aqueous suspension with PTFE particles in a spin-coating process, obtaining a hydrophobic behavior. Then, the electrospraying of a modified PTFE dispersion forms a layer of distributed PTFE particles, in which a strong bonding of the particles with each other and with the PTFE particles fixed in the PAA + β-CD fiber matrix results in a remarkable improvement of the particles adhesion to the substrate by different heat treatments. The experimental results corroborate the important role of obtaining hierarchical micro/nano multilevel structures for the optimization of superhydrophobic surfaces, leading to water contact angles above 170°, very low contact angle of hysteresis (CAH = 2°) and roll-off angle (αroll−off < 5°). In addition, a superior corrosion resistance is obtained, generating a barrier to retain the electrolyte infiltration. This study may provide useful insights for a wide range of applications
Restringido
Systematic isotopic marking of polymeric components for in-situ space missions
(Elsevier BV, 2020-02-01) Mora, J.; García Sancho, Amador; Alonso, R.; Atienza, R.; López Reyes, G.; Sanz Arranz, A.; HERRERA HERNÁNDEZ, ALEJANDRO; López Reyes, G. [0000-0003-1005-1760]; Unidad de Excelencia Científica María de Maeztu Centro de Astrobiología del Instituto Nacional de Técnica Aeroespacial y CSIC, MDM-2017-0737
In the last decades, together with the technological advances, the exploration of closer celestial bodies has experimented a high increasing, with a special relevance of the missions whose objective is the scientific search of life precursors. Since the birth of COSPAR (Committee on space research) in 1964, many advances have been achieved in terms of Planetary Protection, to avoid introducing terrestrial contamination in other systems, and/or come back with extraterrestrial contaminations in sample return missions. Many restrictive protocols are adopted by space missions to minimize the bacteriological, molecular and particle contaminations, and especially harder in scientific missions, where the risk of a false positive in an analysis due to terrestrial contamination is critical. These missions search for small quantities of organic material, and any trace of simple signals of C–H, C–O, C–C, C–N, etc. bonds are the target. Many of these signals are present in all the polymeric components used in a space vehicle, and any accidental or natural contamination could lead to a false positive detection of precursors of life. In this work, a new protected technology to avoid any doubt in these cases is proposed: the systematic isotopic marking of polymeric materials used in space missions. As proof of concept, polyethylene terephthalate (PET) polymers, with the same characteristics of the one used in the calibration target for the Raman Laser Spectrometer (RLS) in the ExoMars mission, were synthetized in three different ratios of deuterium marking: 0%, 35%, and 100%. In addition the calibration target of the SuperCam instrument of the Mars 2020 mission also includes a sample of PET. The polymeric characterization by Thermo-gravimetric analysis (TGA) and Differential scanning calorimetry (DSC) showed similar characteristics, in the range of commercial PET polymers. The same analytical techniques used for organic studies, on board of the ExoMars laboratory, were used for this study: Raman spectroscopy, and Gas chromatography with mass spectrometry (GC/MS). Results showed that both marked compositions could be unequivocally identified, due to the expected differences caused by the increasing of mass of the marked hydrogen atoms. The materials were subjected to the outgassing test, according to ECSS-Q-ST-70-02C standard, of mandatory compliance for every material used in a space mission following the European standards ECSS, to test the validity for space use. All materials, marked and unmarked, passed this test, and even a slight improvement in RML could be observed in the fully deuterium marked (100%) PET, probably caused by its higher weight, but further studies are needed to verify this trend.